LTSpice is simple as a package. it only gets complicated when you try to simulate complicated circuits. Start with the basics, then progress. There are some that dont like it, but for a free of charge simulation package, it is the best you can... erm... buy (get?). Have a look at my LTSpice tutorial. You will be hooked in a couple of hours and never look back:
http://www.simonbramble.co.uk/lt_spice/ltspice_lt_spice.htm
Analogue electronics will no longer be the black art that everyone makes it out to be