In TO-3 package the case is collector. You can find out the structure with diode-checker or multimeter: connect +wire to pin1 -wire to other pin,afterward -wire to case.If You find with this method two conducted diodes,it`s NPN transistor,and +wire the base.If nothing found, change polarity..... nothing found connect the + to another pin....
I hope You can understand my bad english,unfortunately i never learn.Maybe help for You.