So bearing in mind the aim of my original question and all the excellent informative replies, it sounds as if all one really needs to do for a quick and dirty solution is connect the LED to the intended voltage with some high value series resistance and gradually reduce this till the LED is bright enough to be visible.
Pretty well
However, I would (not 'quite' as crudely
So 12V supply, you want 10mA - so simply 12/0.01 = 1200 ohms.
Obviously the actual current will be less than 10mA, and is more inaccurate with lower voltages - but for a simple 'connect and make sure it lights up' it's 'near enough'