Thanks Doc , I did see this design but had parts for build "In stock"
spec, thanks for reform post , I tried it on the 12,000 uF cap ( only 20v) and it would appear OK .
For this class of caps....leakage can be defined in worst case for new condition or re-conditioned.
I = .006 √ CV
Not to exceed 6.0 mA max. after 5 minutes, C = Capacitance in µF , V = Rated Voltage, I = Leakage current in mA
Thus after 5 minutes leakage current on 12 mF at say 24Vdc should be < 0.006 * √ ( 0.012 * 24) = 3.2 mA max which is equivalent to 7.5 kΩ minimum across 24Vdc.
Although rarely specified each family of caps has a uniform Rp leakage * C time constant which can be
ms to hours for Teflon caps, but in this case 0.09 seconds minimum.
But as noted before Absorption capacitance can have a much longer time constant with high ESR and higher effective parallel resistance.. with time constants in minutes.
The ESR *C also has a relatively constant value in each family of caps which is affected by material, size , temp and rated voltage.
For this class of Cap the ESR*C constant is around 100~200 microseconds. "ultra Low ESR types" would be in the range of 1~10 μs.
So you can expect the ESR of this 12mF cap to be in the range of 15 mΩ give or take a wide margin.
Although an arc strikes on short circuit in picoseconds, it would take couple hundred microseconds to discharge, the residual charge that raises the voltage is due to aging effects of Dielectric Absorption, which doesn't make the cap bad, but does require re-conditioning.
The energy stored would be 1/2CV^2 which at 24V is only 3.5 watt-seconds or Joules
So you could charge up the cap to 24V to 30V and it could power a string of 6 White LEDs or ~18V and with 6 to 12V drop use 300Ω and get 20 to 40mA peak current dropping to dim in about 5 seconds then run on a few mA for much longer.
Does that help?