1) I don't know the wavelengths for the colours used on a TV screen, have you tried Wikipeida?
2) Yes, of course the spectrum will consist of red and green, not yellow when a light from a yellow pixel on a screen is analysed.
Look up RGB model and colour vision - there's nothing special about the wavelengths for red, green and blue, they're just the pass bands for the cone cells on the human retina.