I use LTspice, does PSpice have an Initial Condition Directive.???
In LTS , I would set the Initial Condition on Pin2 of the 741, by using .IC (V(pin2)) = 5V Give pin2 a Label Name and use that Name in place of (pin2) in the Directive.
EDIT: I think your pin2 Name is 'A'.? so .IC(V(A))=5V