yeah i was assuming you wanted something on the order of less than 50 vdc to buck down to 8-20 volts.
I'm not familiar with most electrolysis set-ups other than trying to make sodium from table salt at 800C, or making hydrogen and oxygen from car batteries at 18 volts and 30 amps per battery...
but 100 amps seems insane, seems to me that much current would be used to anodize an entire 4 by 8 foot sheet at one time.
and as far as i know once the initial annodization is done, you need a few hundred volts at mere milliamps to get that nice hard thick layer of aluminium oxide.. and then you take the part out and quickly dump it in the dye solution so the crystals of Al2O3 suck up the colourizing agent...
in anycase, 1Khz was on the slow side 30 years ago. bipolar darlingtons can get you reasonable losses at up to 10Khz, and mosfets are good to 500Khz today.
my calculations at 100 volts in, 10 volts out and 100 amps at 1Khz and 1 volt drop across the switch, and 1 volt drop across the diode mean you're going to be running at about 10.2% duty cycle and for 10 amps of peak to peak ripple current means you need 505uH inductor. and its going to store 3 joules of energy.
the output capacitor is only going to see 5.7 amps of ripple current, and you're going to need 25,000 uF
the input capacitor is going to see 33.389 amps of ripple current and you need a minimum of 3000 uF
oh, with a buck regulator you're not getting something for nothing either...if you're worried about the diode losses i would recommend just making your own 100 amp 10-20 volt transformer and running that into a stack of 30 amp 45 volt Schottky diodes which only have a .5 volt forward voltage under rated load... well heatsinked (you can parallel them, provided they are from the same manufacturer)
run the transformer from a variac.