What You've found is only the product summary.
The whole Datasheet you can find at the ATMEL Pages
http://www.atmel.com .
The Product line is 8Bit AVR Controller
The direct URL to your Datasheet is:
https://www.electro-tech-online.com/custompdfs/2012/03/doc8272-6.pdf
There is a USART Section that starts on Page 174.
The whole Datasheet has 584 Pages!
MAX 232:
The Controller only give out voltages of 0V and +5V on it's USART Output.
For a regular RS232 interface you have to use -12..15V and +12..15V.
A MAX232 has 2 Charge Pumps, 2 Outgoing Level Shifters and 2 Incoming Level Shifters.
In Most Applications only one Outgoing Level Shifter is used for TxD of the Controller and one Incoming Level Shifter was used for RxD.
Thats enough to built a Connection between the PC and Your Microcontoller circuit.
Sometimes the other 2 Level Shifters were used for the RTS and CTS.
FT232Rx:
The FT232RL is a USB Bridge from FTDI. There are 2 Drivers for such Chips availible.
The D2xx Driver that give full access to the chip and the VCP ( Virtual Com Port ) Driver.
You should use the VCP Driver. When that driver is installed on your computer every connected FT232R was indicated as serial Interface.
You can Handly it with many Terminal Programms like Hyper Terminal and so on.
At the Output to the Microcontroller it has 0V, 5V Level. That fits to your Microcontroller.
I wouls suggest you to prefer that solution, because the normal serial Interfaces were not longer supported by most Motherboard manufactors.
Additional you should decouple the FT232Rx Part from the Rest of your Circuit by Using Opto Couplers.
How to do that you can see here:
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The FT232Rx Part is on the right Bottom of the Schematic.
Near at the Bottom of the Page are Schematics and Layout for the PCB Program "EAGLE"
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Settings:
In what Operation Mode the Controller should work syncronos/ asynchronos?
What speed you want to use 9600bps or 38400bps?
How many Stop bits you want to use 1 or 2?
Do you want to use a parity bit, when yes with sum, even or odd?
Do you want a interrupt driven transmission and receiving?
All that settings must be done in the initialisation section of your Controller program.
When that's be done and the USART is interfaced to your Computer, by Level Shifter or USB Bridge, you can write a Input and Output Routine for the comunication between your Microcontroller and the PC.