This is what I have in my 4WD:
Battery 2 pos. is connected to battery 1 pos. via a 60Amp relay. Relay coil is connected to ignition circuit. Both batteries neg. connect to chassis.
Operation: engine (diesel) off; battery 2 supplies in car fridge, 2 way radio's & fluoro light in the back. I have a battery voltage monitor fitted and also wiring to a charger for external charging if mains power is available.
Engine on, relay connects both batteries in parallel.
It does not get any simpler than this.
There are fancy battery isolators available but most suffer from a voltage drop, meaning battery 2 never gets fully charged - unless some booster device is also used.
Klaus