I would agree if we're talking about 1kVDC vs 1kVAC.
However, in this case we're talking about 94VDC vs 230VAC, it's pretty obvious that the AC is far worse here.
The IEE regulations even seem to agree that AC is more hazardous than DC, the minimum touch voltage is 25V for AC and 60V for DC. You could build a power supply with a 30V mains transformer but you only have to protect the user from the mains and the 30VAC on the transformer's secondary, not the 41VDC present on the output of the rectifiers, to comply with the IEE regulations.
By the way, AC can also make you freeze, my mum told me a story about a neighbour who nearly got electricuted from by a dodgy electric drill; he couldn't let go of it, the current had frozen his mussels.