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After all this point stretching, no one seems to have realised that Saiello never said he was limited to 5V to power the stretching circuit, he only stated that the photodiode produced an output pulse of 5v amplitude.
He may well have an independant supply voltage available e.g. 12 or 24v from which to power the subsequent circuit. Therefore perhaps the bulk of this discussion has been a waste of space, though nonetheless informative lol.
Holy smoke, never thought my little post would generate so much 'debate'..!
If I can't get this improvement with nothing more than the addition of a few simple passive components then I'll just stick to what already works..!