Unlike a conventional fuse, the actual current at which a polyfuse will trip depends on several factors.
The ambient temperature affects the fuse rating, as does the amount of 'extra' current flow, and the time a taken for the fuse to trip will depend on the temperature rise, caused by a specific excess current flow.
In the case of a 'dead short' everything happens pretty quick. In the case of just a small excess current, the fuse can take a while to 'blow'.
The datasheets show the graphs, but it can be difficult to be precise, because of the variable temperature involved.