Unless you are planning on using an RF module for communication that has some intelligence built into it, you will need a way to syncronise and recover your clock at both ends of the link. This is usually achieved by using a signal encoding method of some type, most commonly Manchester.
Without being able to sync and recover your clock, there will be no reliable way to send/ receive data.
I see from your schematic that you have two Micro's, LED's and a switch, but where are your transmitter/ receiver modules etc?
You will not be able to use the standard built in UART for your RF link, you will need to write the code for both transmit and receive and bit bang a couple of port pins. I have a vague memory that Nigel Goodwin has an example and tutorial of how to do this on his site, but I could be wrong. His tutorials are worth a look through in any case
rgds