that won't be very reliable though, because unequal loads on the + and - supplies will cause the batteries to discharge at different rates.
you could use a MAX660 and provide it with +9v, and it outputs -9v. from what i've heard though it doesnt' provide a very clean output so if you need a precision -9v, you should output something like -12v and then use a 79L09 regulator to regulate it down to a clean -9v.