Below 60 vdc or 42 v peak or 30 vrms is "safe."
Only one person in the whole history of the U.S. Navy got electrocuted on a voltage as low as 47v.
1 mA current through your body is detectible, 10 mA is painful, 20 mA you can't let go, >100 mA could be fatal.
Current through your chest is worse than current through your fingers.
Cardiac defibrillators put out up to 7 watt-seconds [joules] of energy, and they are dangerous.
For extra credit, look up "arc flash" and "skin resistance".
>600 v punctures the skin and, for me, it left a little hole that took a while to close up!
Your questions is a pretty general non-specific one so I will give a general answer. "Electronics men" safety would be following rules and practices that would prevent injury to self or others due to unsafe acts or practices.
Oh yea, it's also not a good idea to solder while wearing shorts.
Don't set the circuit board for a CCFL bulb on a pair of jeans you're wearing and then plug it in. Those sharp points seperate the jean threads nicely and provide adequate conduction to make your leg itch from a minor 1st degree burn for hours.