The series circuit offers a higher total voltage rating. The voltage drop across each capacitor adds up to the total applied voltage.
Caution: If the capacitors are different, the voltage will divide itself such that smaller capacitors hog more of the voltage! This is because they all get the same charging current, and voltage is inversely proportional to capacitance.
Worse yet, if one capacitor is slightly leaky, it will gradually transfer its voltage to the others, possibly exceeding their voltage rating in turn. And if one of them punches through its dielectric barrier, it can then damage others in a cascading fashion. This is why series capacitors are generally avoided in power circuits.