Your description sounds too complicated. I am not sure I could give you a good answer but here goes:
If both rollers' sensor circuits produce a 0-10V signal, then you can simply use an op-amp to calculate the difference and produce an error signal. This error signal can be input to an analog PID circuit which can output a 0-10V that canl be fed into the vfd.
BTW, what's a vfd?
Maybe there are easier ways like dividing down the frequency out from the 600rpm roller by 6 and comparing the frequency after division to the 100rpm roller. This works like a phase locked loop.