Hello there,
One of the simplest methods for measuring temperature with a PIC (or just a trip point temperature) is to use a resistor from the +5v supply to the thermistor and connect the other end of the thermistor to ground. The junction is then fed to an AD input pin and the voltage measured with the PIC. The voltage is then converted into temperature with a short formula that uses the curve of the thermistor within the PIC code. The result is an estimate of the temperature of the thermistor.
The curve uses at least two constants A and B and the curve itself is basically the same for any thermistor. The nice thing is if your temperature is limited to some smaller range then the formula is a lot simpler.
If you only have to detect a trip point then you dont even have to do that. All you have to do is calculate the voltage (or just measure it) when the thermistor is at your set point temperature and then in code tell the PIC to detect that voltage. For example, with a thermistor rated for 10K ohms at 25 deg C, if you use a 10K ohm resistor from +5 to the thermistor and you want to detect 25 deg C all you have to do is look for 2.5v as that will be the correct voltage for 25 deg C.
If i remember right, for a single temperature like this you get the best sensitivity when the resistor is the same value as the thermistor at the given temperature. For example, if that same thermistor is 20k ohms at the required temperature then use a 20k ohm resistor instead of 10k. You will then still be looking to detect 2.5v. It's that simple.
Calibration would be as simple as heating (or cooling) the thermistor to the required temperature and either adjusting the 20k ohm resistor or adjust the detect voltage in code slightly.