The most important question is whether the RS232 link is in one direction or both?
Does the RFID reader just throw out the tag ID when it sees a tag, or does the PC have to ask for it?
If it is one direction, you can put a transmitter on the RFID reader and a receiver on the RS232 - USB converter.
If it is two directions, you could use two frequencies, one for each direction.
Or you could have a microcontroller that asks the RFID reader for the tag ID, and transmits the reply by wireless to another microcontroller. The second microcontroller is connected to the RS232 - USB converter and pretends to be the tag reader, and replies to the PC with the tag numbers.